Assessment of indoor radon distribution and seasonal variation within the Kpando Municipality of Volta Region, Ghana.

This study uses CR-39 radon detectors to examine radon distributions, seasonal indoor radon variations, correction factors, and the influence of building materials and characteristics on indoor radon concentration in 120 dwellings. The study also determines the spatial distribution of radon levels using the ArcGIS geostatistical method. Radon detectors were exposed in bedrooms from April to July (RS), August to November (DS); December to March (HS), and January-December (YS) from 2021 to 2022. The result for the radon levels during the weather seasons were; 32.3 to 190.1 Bqm-3 (80.9 ± 3.2 Bq/m3) for (RS), 30.8 to 151.4 Bqm-3 (68.5 ± 2.7 Bqm-3) for HS and 24.8 to 112.9 Bqm-3(61.7 ± 2.1 Bqm-3) for DS, and 25.2 to 145.2 Bq/m3 (69.4 ± 2.7 Bqm-3). The arithmetic mean for April to July season was greater than August to November. The correction factors associated with this study ranged from 0.9 to 1.2. The annual effective dose (AE) associated with radon data was varied from 0.6 to 4.04 mSv/y (1.8 ± 0.1 mSv/y). The April to July period which was characterized by rains recorded the highest correlation coefficient and indoor radon concentration. Distribution and radon mapping revealed radon that the exposure to the occupant is non-uniformly spread across the studied dwellings. 15.4% of the studied data exceeded WHO reference values of 100 Bq/m3. The seasonal variation, dwelling age, and building materials were observed to have a substantial impact on the levels of radon concentration within the buildings.

Ecological and human health risk assessment of potentially toxic elements in water and soils within a crude oil waste management facility, Southwestern Ghana.

Crude oil waste management is challenging due to the diverse constituents of the waste and its consequent impact on valued environmental receptors (water and soil). Characterization of the potentially toxic elements (PTEs) in soils and water within the surroundings of crude oil waste management facility is imperative, to aid evaluation of potential risks. The study assessed the potential environmental and human health risks posed by PTEs in soil and water from surroundings and adjoining settlement communities. A total of forty-four (44) samples were analyzed for PTEs (Cr, Pb, Zn, Co, Mn, Ni, Hg, Fe, As, Cu, Hg, and Cd) and physicochemical properties in both matrices. The total carcinogenic risk (TCR) for adults and children in the neighbouring community was 4.73 × 10-6 and 1.2 × 10-4, respectively, which was due to the high carcinogenic slope factor of arsenic. A strong correlation was observed between the PTEs and physicochemical properties, and their health risk was attributed to both geogenic and anthropogenic factors. The study indicated that the human health and ecological risk values obtained were within acceptable limits, with the waste management facility posing a higher risk in comparison to the nearby community. These risks may be attributed to the specific nature and intensity of the activities conducted at the facility. Hence, there is the need for continuous promotion of occupational and public awareness on the health and environmental impact of crude oil waste management.

Assessment of natural radioactivity, radon gas and soil characteristics along the Volta Lake in the Kpando municipality of Volta region, Ghana.

Assessment of radionuclides, indoor radon (222RnI), radon exhalation (222Rnex), and soil characteristics in the coastal part of Kpando has been studied using HPGe, CR-39 and sieving techniques. Statistical analysis between radionuclides, radon levels and soil characteristics was done using Pearson's correlation. The mean radionuclide concentration, radon levels and soil characteristics were obtained as 226Ra (23.1 ± 1.4 Bq per kg), 232Th (34.6 ± 2.9 Bq per kg), 40K (187.1 ± 13.7 Bq per kg), 222RnI (64.70 ± 2.7 Bq per m3), 222Rnex (7.9 ± 0.5 µBq per m2h), sandy (45.9 ± 3.9%), silt (40.7 ± 3.1%), clay (13.5 ± 0.8%), porosity (0.6 ± 0.1) and moisture (7.6 ± 0.8%). Radiological effects estimated were within recommended limits. The maximum positive and negative coefficients exist between 222Ra/222Rnex (1.0) and 222Rnex/MC (-0.9), respectively. Radon exhalation correlates better with soil characteristics. The statistical analysis indicated that soil characteristics have significant effects on radionuclides and radon levels in soils and dwellings.

Radon mapping, correlation study of radium, seasonal indoor radon and radon exhalation levels in communities around Ghana atomic energy commission.

Radon mapping and seasonal radon studies have been carried out within the communities around the Ghana Atomic Energy Commission (GAEC), using ArcMap geostatistical interpolation tool. The correlation analysis was done using Pearson's correlation tools. Average seasonal indoor radon variations for CR (rainy) and CD (dry) with mean values ranging from 28.9 to 177.2 Bq/m3 (78.1 ± 38.7 Bq/m3) and 24.4-125.5 Bq/m3 (69.9 ± 24.2 Bq/m3). Average seasonal soil radon exhalation for ER (rainy) and ED (dry) with mean values ranging from 39.6 to 100.3 (68.9 ± 24.2 µBq/m2 h) and 55.2 to 111.9 (77.1 ± 18.7 µBq/m2 h). Radium concentrations ranged from 8.1 to 42.2 Bq/kg (21.3 ± 9.9 Bq/kg). Annual effective dose and resultant effective dose to lungs were found to be 0.9 to 2.9 (1.9 ± 0.8 mSv/yr), 2.1 to 9.2 (4.6 mSv/yr). The study recorded the highest and lowest positive correlation coefficient was found in the study with higher and lower coefficient values of 0.81 and 0.47 recorded in radium concentration with radon exhalation and indoor radon concentration within the dry season respectively. Pearson correlation result recorded values 0.81 and 0.47 as the highest and lowest positive coefficient values for the radium concentration correlation between radon exhalation and indoor radon concentration. One directional principal component was observed in radium concentration, seasonal radon exhalation, and indoor radon concentration. Two clusters originated from radium and seasonal radon concentrations present in dwellings as well as soils. Pearson's correlation results were in agreed with the principal component and cluster factor analysis. The study obtained the highest and lowest indoor radon concentrations with radon exhalation in rainy and dry seasons. Radium concentration was found to have a considerable effect on indoor radon and radon exhalation in dwellings and soils.

Performance testing and comparative study of natural radioactivity in soil samples using high purity germanium (HPGe) detector.

High Purity germanium (HPGe) detectors are found to be suitable for nuclear techniques for measuring radionuclides with very good energy resolution. Inter-comparison exercise is an important tool for external quality control that enables determination of the accuracy and uncertainty of detector measurement system. In this work, a comparative study of natural radioactivity in soil samples was conducted between the laboratory of Autorité nationale de Radioprotection et de Sûreté Nucléaire (ARSN), Burkina Faso and the laboratory of Radiation Protection Institute of Ghana Atomic Energy Commission (RPI-GAEC),Ghana to ascertain the reliability and accuracy of measurements made in Burkina Faso. For this purpose:•Some replicate soil samples, assumed as proficiency test samples, were analyzed on both the High Purity Germanium detector of ARSN and RPI.•The statistical performance indicators of z-score, precision, trueness and relative bias were used for the evaluation. The limit for acceptable precision and the maximum acceptable bias for all the radionuclides were set to 20% and 15% respectively.